José C. Iñiguez
Centro de Investigación en Termodinámica y Fenómenos Auto-Organizativos,
CITER, Av. Panamericana 357, Agua Prieta Sonora, México 84200, Mexico.
E-mail: [email protected]
Received: 19 October 1999 / Accepted: 26 October 1999 / Published: 30 October 1999
Abstract: Carnot's reversible cycle net value was determined using the previously derived values for the transformations there occurring. A negative net value is obtained as a result, in contradiction with current thermodynamics, Clausius analysis based position that the net value for such a cycle is zero. The entropy function is introduced and the new criterion's for spontaneity, reversibility and equilibrium are advanced.
Keywords: Clausius, cyclical processes; entropy; negentropy; umbral efficiency.