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Section A. General Organic Synthesis

Section Convener: Prof. C. Oliver Kappe, University of Graz (Austria), Institute of Chemistry, Karl-Franzens-University Graz, A-8010 Graz, Austria.
Fax: ++43-316-3809840, E-mail: [email protected]

Reviews

[A0001]  New heterocyclic materials by new MCRs and domino reactions
Tomás Torroba*, Oleg A. Rakitin and Charles W. Rees

[A0002] Synthesis of Polycyclic Ring Systems Using Transition Metal Catalyzed Cyclizations of Diazo Alkynyl Ketones
Albert Padwa

[a0003] 3-Dimethylaminopropenoates and Related Compounds in the Synthesis of Heterocyclic Systems and Heterocyclic Amino Acids
Branko Stanovnik

[a0004] Organic Iodine(I, III, and V) Chemistry: 10 Years of Development at the Medical University of Warsaw, Poland
Lech Skulski

Posters

[a0005] Preparation of new enantiopure atropisomeric b-aminoalcohols and their use in asymmetric catalysis: enantioselective addition of diethylzinc to aromatic aldehydes
Tommaso Mecca, Stefano Superchi and Carlo Rosini*

[a0006] Solid state isomerisation of atropodiastereomers: A promising method to obtain high diastereomeric ratios
Cathy Einhorn, Andre Durif, Marie-Therese Averbuch and Jacques Einhorn*
Withdraw after the conference

[a0007] Asymmetric synthesis of cis-4,5-disubstituted oxazolidin-2-ones via chiral a-amino epoxides derived from L-Serine
F. Javier Casado-Bellver, Eugenia Gonzalez-Rosende, Amparo Asensio, Patricia Cava-Montesinos, J. Miquel Jorda-Gregori and Jose Sepulveda-Arques*

[a0008] Crystal and molecular structures of N-benzyl-C-(2-pyridyl)nitrone and its ZnBr2 complex
Pedro Merino*, Sonia Anoro, Tomas Tejera, Mariano Laguna, Elena Cerrada and Ana Moreno

[a0009] Synthesis of Glycals and Oligosaccharides of Deoxysugars via Catalytic Endo-Selective Alkynol Cycloisomerization
Frank E. McDonald* and K. Subba Reddy
Withdraw after the conference

[a0010] Strongly Fluorescent Push-Pull Substituted Carbostyrils Absorbing in the Visible
Georg Uray*, Gernot A. Strohmeier and Walter M. F. Fabian

[a0011] A New Photochemical Route to Cyclopropanes and Bicyclo[n,1,0]alkanes
O. Mühling and P. Wessig*

[a0012] Stereoinduction in the Tosyl Radical-Mediated Cyclization of Polysubstituted 1,6-Dienes Derived from D-Glucose and D-Mannose
Dora-Marina Gutierrez-Avella, Michele Bertrand* and Robert Nouguier*

[a0013] Synthesis of 5-Substituted a,b-Unsaturated g-Lactams from N-Sulfinyl Azadienes by Iron-mediated Reaction Cascades and Palladium-catalyzed Cyclocarbonylation Strategies
Patrick Amrhein and Karola Rück-Braun*

[a0014] Asymmetric Syntheses with a New Nitrogen Containing Chiral Diselenide
M. Tiecco, L. Testaferri, C. Santi, C. Tomassini, F. Marini, L. Bagnoli and A. Temperini

[a0015] Enantioselective Intramolecular CH-Insertions upon Cu-Catalyzed Decomposition of Phenyliodonium Ylides
Paul Müller and Christelle Boléa

[a0016] Asymmetric 1,3-Dipolar Cycloaddition Utilizing Tartaric Acid Ester as a Chiral Auxiliary
Yutaka Ukaji and Katsuhiko Inomata*

[a0017] Synthetic Applications of the Asymmetric Amino-Cope Rearrangement
Rob D. Baird, Martin A.C. Button and Steven M. Allin*

[a0018] Polymalonates Derived from ortho-Bromomethylated Tetraarylporphyrins
Norbert Jux

[a0019] The 1,2,4-Triazolyl Cation: Thermolytic and Photolytic Studies
Rudolph A. Abramovitch*, Harry H. Gibson, Jr. and Santiago Olivella

[a0020] Nickel-promoted Reductive Cleavage of Nitrogen-nitrogen and Nitrogen-oxygen Bonds Mediated by Lithium and a Catalytic Amount of an Arene or Polymer Supported Arene
F. Alonso, P. Candela, C. Gomez, J. Gomis, A. Guijarro, F. F. Huerta, E. Lorenzo, R. Perez, J. J. Ortiz, I. Pastor, G. E. Radivoy, P. Ronda and M. Yus*

[a0021] Arene-Catalysed Reductive Cleavage of the Benzylic Carbon-Sulfur Bond: Generation of Benzylic Lithium Reagents
E. Alonso, J. V. Ferrandez, F. Foubelo, I. Gomez, D. Guijarro, A. Gutierrez, P. J. Martinez, O. Prieto, D. J. Ramon, T. Soler and M. Yus*

[a0022] Asymmetric Synthesis of Functionalized Prolines by Diastereoselective 1,3-Dipolar Cycloaddition Using Chiral Oxazinone Derivatives
Rafael Chinchilla, Nuria Galindo, Patricia Mazon and Carmen Najera*

[a0023] Efficient allylation of 4-silyloxy quinolinium triflates and other positively charged heteroaromatic systems
Uwe Beifuss* and Ursula Schniske

[a0024] Enzyme-mediated Synthesis of (1S)-1-Amino-2,2-dimethylcyclopropane-1-carboxylic Acid
Antonio Salgado, Annelies Eeckhaut, Norbert De Kimpe* and Johan Van der Eycken

[a0025] A Convenient Synthesis of cis-3-Hydroxy-L-Proline
Surajit Sinha, Santosh Tilve and Srinivasan Chandrasekaran*

[a0026] The Aminopalladation-Reductive Elimination Tandem Reaction in the Construction of the Functionalized Indole Ring
Sandro Cacchi*, Giancarlo Fabrizi and Fabio Marinelli
Withdraw after the conference

[a0027] Base promoted isomerization of aziridinyl ethers: a new access to a- and b-aminoacids
Laura Sbaragli, Francesco Russo, Michela Valacchi, Gianna Reginato, Alessandro Mordini*

[a0028] Palladium(II) Supported by Hydrotalcite[Pd(II)-Hydrotalcite]-Catalyzed Selective Oxidation of Alcohols Using Molecular Oxygen
Nobuyuki Kakiuchi, Takahiro Nishimura, Masashi Inoue and Sakae Uemura*

[a0029] Synthesis And Electrophilic Substitution of Pyrido[2,3,4-kl]acridines
Avi Koller, Amira Rudi, Marta Garcia Gravalos and Yoel Kashman*

[a0030] 1,3-Dipolar Cycloaddition Reactions with Azomethine Ylides Catalysed by Ag(I). Synthesis of Substituted Prolines
Tomas Abellan, Jesus Casas, Ana Costa, Carmen Najera* and Jose M. Sansano

[a0031] (S)-5-(Tosylmethyl)-2-pyrrolidinone: A New Chiral b-Amidosulfone for a Short Asymmetric Synthesis of Indolizidines
Tomas Abellan, Diego Alonso, Jesus Casas, Ana Costa, Carmen Najera*, Jose M. Sansano and Montserrat Varea

[a0032] New Chiral Phase Transfer Supported Catalysts in The Asymmetric Synthesis of a-Amino Acids: The Importance of a Spacer
Dominique Cahard*, Baptiste Thierry and Jean-Christophe Plaquevent

[a0033] Epoxidation Studies of Decalin-1,4-dienones and Related Alcohols
Guillermo R. Labadie, Raquel M. Cravero and Manuel Gonzalez-Sierra*

[a0034] Copper Mediated Addition of Organozinc Halides to N-benzyl Benzenesulfonimine
David Rosenberg, Jason Kraska and Reuben D. Rieke*

[a0035] Facile and stereoselective synthesis of enantiomerically pure trifluoroalanine
Marcello Crucianelli*, Natalia Battista, Pierfrancesco Bravo, Alessandro Volonterio and Matteo Zanda*

[a0036] Synthesis of Enantiomerically Pure Pipecolic Acid Derivatives via Combination of Biocatalysis and Transition Metal Catalysis
Sape S. Kinderman, Jetze W. van Beijma, Larissa B. Wolf, Hans E. Schoemaker, Henk Hiemstra and Floris P. J. T. Rutjes*

[a0037] A Comparison of Two Effective Chiral Auxiliaries - (2R)-bornane-10,2-sultam and (2R)-bornane-10,2-cyclohydrazide - using the [4+2] Cycloaddition of Cyclopentadiene to their N,N'-fumaroyl derivatives
Christian Chapuis*, Anna Kucharska and Janusz Jurczak*

[a0038] 4,5-Disubstituted Pyrrolidin-2-ones starting from D-Xylose
Cristiana Fava, Roberta Galeazzi, Giovanna Mobbili and Mario Orena*

[a0039] New Fluorous Chiral Phosphorous Ligands Based on the Binaphthyl Skeleton
Marco Cavazzini, Amedea Manfredi, Fernando Montanari, Gianluca Pozzi* and Silvio Quici

[a0040] Ring Closure Reactions of 4-Chloro-5-hydroxyalkylamino-6-nitro-3(2H)-pyridazinones: Synthesis of Novel Pyridazino-Fused Ring Systems
Oliver Elias*, Laszlo Karolyhazy, Geza Stajer, Veronika Harmath, Orsolya Barabas and Peter Matyus
Withdraw after the conference

[a0041] Reductive Ring Opening of Cr(CO)3-Complexed b-Lactam Ring: Stereoselective Synthesis of Dihydrobenzopyran
Paola Del Buttero and Laura Casiraghi

[a0042] A general, high-yielding synthesis of b-diamides and b-amidoesters
Pilar Lopez-Alvarado, Carmen Avendano and J. Carlos Menendez

[a0043] An Unexpected Result from a 1,3-Dipolar Cycloaddition: Synthesis of Pyrrolo[1,2,3-de]quinoxalines
Raymond C F Jones*, James N Iley and Pedro M J Lory

[a0044] Selective Deprotection of Thioacetals by MnO2, BaMnO4 and KMnO4 in the Presence of Anhydrous AlCl3 and FeCl3 in Dry CH3CN
Habib Firouzabadi*, Hassan Hazarkhani, Babak Karimi, Uranous Niroumand and Soheila Ghassamipour

[a0045] Characterizing Cavities in Model Inclusion Fullerenes: A Comparative Study
Francisco Torrens

[a0046] Substitution Effects on Reactivity of N-Acyl- 2-amino-2-desoxigliukopyranoses. Quantum Chemical Study
Auðra Vektarienë, Arvydas Juodvirðis and Gytis Vektaris

[a0047] Bicyclic Organophosphorus Fluoridates as Inhibitors of Acetylcholinesterase
S. Furegati, F. Gorla and P. Rüedi*

[a0048] X-Ray Structures of Bicyclic Organophosphates Illustrating the Anomeric Effect
S. Furegati, A. Linden and P. Rüedi*

[a0049] Novel Synthesis of a,b- Diketoesters from a,a’-Dioxo-type Oximes or Oxime Ethers via Zinc-Induced Deoximation
Ilhyong Ryu,* Hiroki Kuriyama, Hironari Miyazato, Mitsuo Komatsu, Joo-Yong Yoon and Sunggak Kim*
Withdraw after the conference

[a0050] Microwave-mediated Regioselective Synthesis of Novel Pyrimido[1,2-a]pyrimidines under Solvent-free Conditions
Jean Jacques Vanden Eynde*, Nancy Hecq, Olga Kataeva and C. Oliver Kappe

[a0051] Synthesis, Resolution and Use in Enantioselective Catalysis of an Axially Chiral Binaphthyl-Templated P,S-Heterodonor Ligand (BINAPS)
Serafino Gladiali,* Serenella Medici, Giovanna Pirri and Sonia Pulacchini
Withdraw after the conference

[a0052] Towards a Selective Activation of Functional Groups Using Monochromatic Light
Celine Helgen and Christian G. Bochet

[a0053] Synergetic effect of urethane formation
Sergiu Coseri* and Adrian A. Caraculacu

[a0054] 3-(2,5-Cyclohexadienyl)-L-alanine (1,4-Dihydro-L-phenylalanine). Its Synthesis and Behaviour in the Phenylalanine Ammonia-Lyase Reaction
Alexander Skolaut and Janos Retey

[a0055] Synthesis of Isoguanosine Analogues
Marjan Jeselnik and Kobe Joze

[a0056] Neighboring Group Participation in the Hydrolysis of Dichloromethyl Carbinols. An Improved Synthesis of a-Hydroxy Aldehydes
George A. Kraus* and Xuemei Wang

[a0057] Diels-Alder cycloadditions of 1,3-cyclohexadien-4,5-diones (o-benzoquinones) with norbornadiene. Part I. Synthesis
Martin R. Johnston, Melissa J. Latter, Ronald N. Warrener, Mirta Golic, Dan McKavanagh and Davor Margetic

[a0058] Diels-Alder cycloadditions of 1,3-cyclohexadien-4,5-diones (o-benzoquinones) with norbornadiene. Part II. A high level computational study of their stereospecificities
Davor Margetic, Martin R. Johnston, Melissa J. Latter and Ronald N. Warrener

[a0059] Halo Aldol Reaction of a,b-Unsaturated Ketones and Aldehydes Mediated by Titanium Tetrachloride
Guigen Li*, Subramanian Karur and Han-Xun Wei
Withdraw after the conference

[a0060] Functionalization of Double Bonds via Cationic Sulfenyl-X Additions
Alexei Novikov and David Goldsmith*

[a0061] First Pd(0)-Catalyzed (Allylic Alkylation / Heck) Domino Sequence
Giovanni Poli*, Giuliano Giambastiani and Barbara Pacini
Withdraw after the conference

[a0062] Enantioselective Palladium Catalyzed Allylic Substitution with New Multichiral Centers Monophosphine Ligands
Jean Michel Brunel*, Martin Smith and Sebastien Reymond

[a0063] A Highly Stereoselective Synthesis of Carbamate Protected anti-1,2-Aminoalcohols
Robert V. Hoffman and Najib Maslouh
Withdraw after the conference

[a0064] Imino-Sugars by Stereoselective Processes Employing Pyrroline N-Oxides
Alberto Brandi*, Stefano Cicchi, Franca M. Cordero and Andrea Goti

[a0065] Rearrangement of Heterocycles Via 2-Oxoketenes. Synthesis and Rearrangement Reactions of Cross-Conjugated Mesomeric Pyridazino[2,3-a]pyrimidines
Barbara Schnell* and Thomas Kappe

[a0066] Study of the Thermal Behavior of Azidohetarenes with Differential Scanning Calorimetry
Wolfgang Stadlbauer* and Gerhard Hojas

[a0067] Indium triflate: An Efficient Catalyst For The Friedel-Crafts Acylation of Aromatics
Christopher G. Frost* and Joseph P. Hartley

[a0068] Microwave Enhanced Synthesis of Acridines. A New Aspect in Bernthsen Reaction.
Julio A. Seijas*, M. Pilar Vazquez-Tato*, M. Montserrat Martinez and Jacobo Rodriguez-Parga

[a0069] N,N-Diisopropylcarbamate of a-hydroxystyrenes: A New Entry to a-hydroxy-b-phenylethylamines and ephedrines
Julio A. Seijas*, M. Pilar Vazquez-Tato* and Luis Barreiro-Castro

[a0070] Synthesis of Styrylamines From b-Methoxystyrene
Julio A. Seijas*, M. Pilar Vazquez-Tato* , Luis Barreiro-Castro and M. Gabriela Onega

[a0071] Microwave Synthesis of 4-Hydroxyquinazolines
Julio A. Seijas*, M. Pilar Vazquez-Tato* and M. Montserrat Martinez

[a0072] The Effect of p-Bond Screening on the Reaction of s-Tetrazines with 7-Substituted Benzonorbornadienes
Ronald N. Warrener* and Peter A. Harrison

[a0073] A New Approach to the Synthesis of Hydrogenated Pyrimidine-2-imines
Anatoly D. Shutalev

[a0074] A Coupling-Isomerization Sequence As An Entry To A Novel Three Component One-Pot Synthesis of 1,5-Benzoheteroazepines
Thomas J.J. Müller* and Roland U. Braun

[a0075] Syntheses of Functionalized Alkynylated Phenothiazines
Thomas J. J. Müller* and Christa S. Kramer

[a0076] The evaluation of b,b,b-trichloro-tert.-butyl (Tcb) group for the protection of carboxyl functionality
Lajos Kovacs*, Peter Forgo and Zoltan Kele

[a0077] Synthetic Methods to Ferrocenomesogens containing a Pendent Ferrocenyl Group
Christopher Imrie*, Christa Loubser, Pieter Engelbrecht, Cedric W. McCleland Nomfuneko Tolom and Vincent O. Nyamori

[a0078] A Divergent, Versatile Synthesis of d-Aminoalkenes and Related Compounds from Carbohydrates; Selective Formation of Polyalkoxypiperidines and Polyalkoxypyrans
Robert T. C. Brownlee, Jason Dang, Helmut M. Hügel, Andrew B. Hughes* and Nuriman

[a0079] Synthesis and Study of Polyelectrolytes on the Basis of Glycidyl Ester of Methacrylic Acid
Nesipkhan A.Bektenov*, Edyl E.Ergozhin, Nazira N.Chopabayeva and Karlygash Zh. Bazarbayeva

[a0080] Ru(II)-Catalyzed RCM Reactions in the Construction of Silacycloalkenes and Silaspirenes
Iftikhar Ahmad, Mette Lene Falck-Pedersen and Kjell Undheim*

[a0081] Enantioselective Electrophilic Fluorination : Two Approaches Using Cinchona Alkaloids
Dominique Cahard*, Christophe Audouard, Jérôme Baudoux, Barbara Mohar and Jean-Christophe Plaquevent

[a0082] Synthesis of 4-Aminopyridine and 4-Acetylaminopyridine by Reduction of 4-Nitropyridine-N-oxide with Iron and Mineral Acids
Vladimir N. Bulavka* and Igor I. Boiko

[a0083] Triarylamine-N-oxides. I. The First Attempt of (4,4´,4´´-Trimethyl)triphenylamine-N-oxide Synthesis and Direct Proof of Its Formation
Vladimir N. Bulavka, Alexandr E. Gekhman and Konstantin K. Koshelev

[a0084] A Chiral Silyl Ether as Auxiliary for the Asymmetric Nucleophilic Addition to a- and b-Silyloxy Carbonyl Compounds
Michael Trzoss and Stefan Bienz

[a0085] Amino Acid-Derived Cyclic Phosphonamides as Potential HIV-Protease Inhibitors
Kevin T. Sprott and Paul R. Hanson*

[a0086] Synthesis of Homochiral R-(+)-2-Methyl-1-butanol
Thomas A. Logothetis and Robert Vleggaar*

[a0087] Stable Carbonyl O-oxides and Dioxiranes
K. Schroeder, K. Block, W. Kappert and W. Sander*

[a0088] Chemistry of Substituted Quinolinones. V. Synthesis and Utility of Quinolinylphosphazenes in Amination of 8-Methylquinoline
Mostafa M. Ismail, Mohamed Abass and Mohamed M. Hassan

[a0089] A Survey of Palladium Catalyst Systems for Cross Coupling Reactions of Aryl Chlorides and Olefins
Alexander Zapf and Matthias Beller*
Withdraw after the conference

[a0090] Preparation and Photochemistry of Thiophene-S-oxides
Thies Thiemann*, Kazuya Arima, Daisuke Ohira, Kazuja Kumazoe and Shuntaro Mataka

[a0091] Memory of Chirality in Alkylation of a-Amino Acid Derivatives
Takeo Kawabata*, Hideo Suzuki, Yoshikazu Nagae, Thomas Wirth, Kiyoshi Yahiro and Kaoru Fuji
Withdraw after the conference

[a0092] Virtual Planar Chirality. A New Approach to Catalyst and Ligand Design
Geraint Jones and Christopher J. Richards*

[a0093] Lewis Acid Catalyzed Enantioselective Reactions Using Highly Coordinating Nucleophiles. Conjugate Additions of Thiols, Thiocarboxylic acids, and O-Benzylhydroxylamine
Shuji Kanemasa
Withdraw after the conference

[a0094] Studies Towards New Reagents for Asymmetric Hydroboration: Synthesis of Racemic Trans-2,5-diisopropylborolane
Kevin J. Hodgetts*, Gerhard Lascober and Massimo Zorzi
 

[a0095] Enantioselective Hydride Abstraction in Organic Substrates: Future Applications for Chiral Carbenium Ions
Derek Magdziak, Liping H. Pettus, Thomas R. R. Pettus*
Withdraw after the conference

[a0096] Synthesis of 2-Nitromethyl-5-nitro-1,2,3,4-tetrazole
Mark V. Rogozin, Konstantin V. Pekhotin, Oksana A. Golubtsova, Rudolf S. Stepanov, Ludmila A. Kruglyakova and Alexander D. Vasiliev

[a0097]trans-(9,10)-Dihydro-11-Aminoethanoanthracene-12-Carboxylic Acid (AMEAC), a New Synthon For b-Peptides
Georg Uray* and Constanze Bergt

[a0098] Triazine based Dendrimers
Christian Dreyer, Alfred Blume, Monika Bauer, Jörg Bauer, Jens Neumann-Rodekirch

[a0099] Synthetic Studies Toward 1a-Hydroxytestosterone from Testosterone
Hongwu Gao and Jerry Ray Dias


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